Multi-walled carbon nanotubes are aligned in a direction. The CNTs are just connected with van der Waals forces, and no binder material is used. The sheet shows high anisotropic transport properties, including electrical conductivity and thermal conductivity.CNT has a multi-walled structure. Crystal quality of CNT is examined by Raman scattering measurement. Intensity ratio of G-peak (1580 cm-1) and D-peak (1350 cm-1) represents quality of graphitization of carbon materials. G/D of CNT is >=3, showing high crystal quality. The high crystallinity is supported by transmission electron microscopy.